Novel Radical Reaction of Phenyteulfonyl Oxime Ethers. A Free Radical Acylation Approach

摘要

Although acylation represents one of the most useful and thoroughly studied reactions in organic chemistry, a successful free radical-mediated acylation is not presently available. Only a few examples, involving highly activated carbonyls such as biacetyl and acyl aldoximes, have appeared to date. It is also noteworthy that free radical carbonylation has recently been reported. This reaction allows the introdution of carbonyl groups to organic halides.