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摘要

This monograph provides a very timely update on the renaissance occurring in the field of supramolecular catalysis. As mentioned by the editor in the Preface, early efforts in the 1970s to apply supramolecular concepts to catalysis focused primarily on replicating how natural enzymes catalyze reactions. The complexity of most of these biomimetic catalysts hampered further application to problems in synthetic chemistry. The goal of developing a selective and efficient catalyst, whether for a synthetic application or as an enzyme mimic, requires the selective recognition of a particular transition state. This book presents a broad spectrum of supramolecular strategies to achieve this goal, ranging from approaches based on molecular recognition and self-assembly to organometallic chemistry.rnThe book comprises 10 chapters written by participants of the 2008 Conference on Supramolecular Approaches to Catalysis in Barcelona. Consequently, it is not intended to be a thorough review of the area but rather represents a concise discussion of the most recent advances in supramolecular catalysis. Although each chapter generally reviews the author's contribution to the field, the chapters flow together smoothly and logically.
机译:这本专着提供了有关超分子催化领域复兴的非常及时的更新。正如序言中编辑所提到的,1970年代将超分子概念应用于催化的早期工作主要集中在复制天然酶如何催化反应上。这些大多数仿生催化剂的复杂性阻碍了对合成化学问题的进一步应用。开发选择性和高效催化剂的目的,无论是用于合成应用还是作为酶模拟物,都需要选择性识别特定的过渡态。本书介绍了实现此目标的多种超分子策略,从基于分子识别和自组装的方法到有机金属化学。本书包括10章,由2008年巴塞罗那超分子方法会议上的参与者撰写。因此,它无意于对该领域进行全面的回顾,而只是对超分子催化最新进展的简要讨论。尽管每个章节通常都会回顾作者对该领域的贡献,但是这些章节顺畅而合乎逻辑地融合在一起。

著录项

  • 来源
    《Journal of the American Chemical Society》 |2008年第52期|18025-18028|共4页
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  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
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