Steric Control in the Thermal Rearrangement of a Bicyclo[3.1.0]hex-2-ene Substituted at a Radical-Nonstabilizing Position

摘要

Introduction into the long-known bicyclo[3.1.0]hex-2-ene system of a large substituent in an electronically inactive, interconnected pair of positions brings to light the importance of sterics as a major factor in the determination of products. Far from t