Synthesis, Resolution, and VCD Analysis of an Enantiopure Diazaoxatricornan Derivative

摘要

Using simple organic synthetic transformations, a novel diazaoxatricornan derivative, the 12c-methyl-12-phenyl-8-propyl-12,12c-dihydro-8H-4-oxa-8,12-diazadibenzo[cd,mn]pyrene (6a), was prepared. This novel chiral cup-shaped molecule was isolated in racemi