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首页> 外文期刊>Journal of the American Chemical Society >Side Selection of the Fifth Coordinate with a Single Strapped Zinc(II) Porphyrin Host: Full Characterization of Two Imidazole Complexes
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Side Selection of the Fifth Coordinate with a Single Strapped Zinc(II) Porphyrin Host: Full Characterization of Two Imidazole Complexes

机译:单束带锌的卟啉宿主的第五坐标的侧面选择:两种咪唑配合物的完整表征

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摘要

Thus, in the case of a phen strapped prophyrin, the strap behaves as the proximal site in the presence of N-unsubstituted imidazoles, due to the presence of a single H bond. This provides insight for the combination of strong and weak interactions for modeling of active sites involving metallopor- phyrins which are under way as well as the magnetic properties of topographically frozen.
机译:因此,在phen附着有卟啉的情况下,由于存在单个H键,在存在N-未取代的咪唑的情况下,该带表现为近端部位。这为强相互作用和弱相互作用的结合提供了见解,用于对正在进行的涉及金属卟啉的活性位点建模以及地形冻结的磁性。

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