A Pyridine-Sensitive Venus Flytrap Porphyrin

摘要

We note that the ligand-triggered αβαβ - αααα conversion could in principle bring together and align appropriate reactive or catalytic groups, as well as provide a mechanism for the controlled delivery of pyridine-containing drug. Its utility in the creaction of shape-selective and chiral oxygenation catalysts and of hemoprotein analogues, will also be explored.